Absolute rate constants for hydrocarbon autoxidation. 25. Rate constants for hydrogen atom abstraction from alkanes by the tert-butylperoxy radical
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منابع مشابه
Rate constants for hydrogen abstraction reactions by the hydroperoxyl radical from methanol, ethenol, acetaldehyde, toluene, and phenol
An important step in the initial oxidation of hydrocarbons at low to intermediate temperatures is the abstraction of H by hydroperoxyl radical (HO(2)). In this study, we calculate energy profiles for the sequence: reactant + HO(2) → [complex of reactants] → transition state → [complex of products] → product + H(2)O(2) for methanol, ethenol (i.e., C(2)H(3)OH), acetaldehyde, toluene, and phenol. ...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1978
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v78-498